Acid Rain - A Problem in the Making?

Spring '98

Period 2 Mr. Congelli

Overly Acidified Precipitation - A Major Problem in the Making?

Overly acidified precipitation and its ramifications are, according to the vast majority of

experts, a very important environmental issue facing the world today. The effects of overly

acidified precipitation (commonly known as acid rain) are slowly and insidiously wearing down the

environment, affecting places in almost every continent. Nevertheless, very few people know what

acid rain is. Nor do many people know what its causes are, the history of our awareness of it, its

effects, or what we can do to stop it. When the general populace comprehends the facts about

acid rain, perhaps they will be able to make a better, more informed decision about the acid rain


To understand the acid rain issue, one must first know what acid rain is. Acid rain is dilute

acids that are given off naturally and by man's constructs. Rain is, naturally, slightly acid. Carbon

dioxide (CO2) which is naturally occurring in our air dissolves in rain water, resulting in the

production of a slight acid. This slight acid is not harmful - it is actually useful because it aids in

the dissolving of minerals, allowing plants, and consequentially animals, to absorb the minerals

with greater ease. (McCormick, 11) But when the precipitation becomes overly acidic, problems

can occur. Humankind has to burn fuel to keep its machines running. When this fuel is burned,

be it coal or a petroleum based fuel, smoke is given off. In this smoke there are agents which

increase the acidity of the water it comes into contact with in the air. (McCormick, 4) Acid rain

can be defined as rain which is harmfully acidic.

A key part of understanding the acid rain issue is understanding what an acid is. An acid

is, generally speaking, a chemical compound that breaks into smaller pieces. These pieces react

with and break apart chemical compounds known as bases. For example, if you mix vinegar (an

acid) with baking soda (a base) the vinegar reacts with the baking soda and breaks it down into

smaller pieces and breaks down itself into smaller pieces which cannot react with each other. This

breaking down quality of acid can be quite derogatory, as we shall see later. Two acids make up

most of acid rain. These acids are SO2 (sulfur dioxide) and NOx (nitrogen oxides) (Ostmann,


The acidity of a substance is expressed as its pH. pH comes from the French "povoir

hydrogene", which is French for "hydrogen power". (Microsoft Corp., 1)

"The term... can be defined as the negative logarithm of the concentration of H+ ions (protons): pH=-log10[H+] where [H+] is the concentration of H+ ions in moles per liter." (Microsoft Corp., 1)

These H+ ions often join together with water molecules to form hydronium (H3O+) ions.

Because of this, oftentimes pH is expressed in terms of the concentration of hydronium ions.

(Microsoft Corp., 1)

"In pure water at 22 degrees Celsius (72 degrees Fahrenheit) H30+ and hydroxyl (OH-) ions exist in equal quantities; the concentration of each is 0.10 (to the seventh power) moles/liter. Consequently, the pH of pure water is -log (0.10(seventh), which equals log(7) or y. If an acid is added to water, however, an excess of H30+ ions is formed; their concentration can range between 0.10(sixth) and 0.10 moles/liter, depending on the strength and amount of the acid. Therefore, acid solutions have a pH between 6 (weak acid) and 1 (strong acid). Inversely, a basic solution has a low concentration of H30+ ions and an excess of OH- ions, and the pH ranges from 8 (weak base) to 14 (strong base)." (Microsoft Corp., 1)

Because the pH scale is logarithmic, a difference of one digit is really a difference of ten

times. A substance with a pH of 2.0 is 10 times as acidic as a substance with a pH of 3.0. A

substance with a pH of 1.0 is 100 times as acidic as a substance with a pH of 3.0. This means that

a difference of just a few tenths in pH, which might not look too important when seen by the

untrained eye is actually a large and potentially important change in acid concentration. (Ostmann,


There are a few ways in which the pH of a substance can be measured. One of these

ways is called titration. Titration is neutralizing the test acid (or base) with a base (or acid) with a

given known pH, with an indicator present. An indicator is a compound whose color changes with

it's pH. The pH of a solution can also be measured directly by taking two special electrodes,

immersing them in the solution, and measuring their electric potential. (Microsoft Corp., 1) Being

able to determine the pH of a substance is a vital element in the study of acid rain.

The causes of acid rain are many. Both man and nature produce the gases which are the

catalyst for the creation of overly acidic precipitation. About half of the sulfur dioxide that is in the

atmosphere today is natural, the rest being man-made. In industrial regions, only about 10 percent

of the sulfur dioxide in the air is natural. (McCormick, 6)

Nature creates about half of the SO2 and NOx in the air. Volcanoes, swamps, and rotting

organic material create sulfur dioxide. (McCormick, 6) Lightning may also constitute part of the

natural NOx in the atmosphere.

"Two strokes of lightning over one square kilometer, or two-fifths of a square mile, produce enough nitric acid to make four-fifths of an inch of rain with a pH of 3.5." (Ray, Dixy lee, 57)

Nature is an important constituent of our acid rain problem, but it is not the one over which we

have control.

The human race creates the other half of the SO2 and NOx in the atmosphere. This is

caused by man's burning of fossil fuels. To keep our factories and vehicles running, we must burn

oil and coal (unless we utilize alternative energy sources such as wind or solar power). When these

fuels are burned, they give off fumes which contain large quantities of SO2 and NOx.. In the UK,

a typical highly industrialized country, 5% of the SO2 and 4% of the NOx came from domestic

heating, 28% of the SO2 and 21% of the NOx came from commerce and industry, 1% of the SO2

and 29% of the NOx came from vehicles, and 66% of the SO2 and 46% of the NOx came from

power stations. (McCormick, 6-7) In one year, the US adds about 30 million metric tons of SO2

and about 26 million metric tons of NOx to our atmosphere. Yearly, mankind adds about 100

million metric tons of SO2 and about 35 million tons of NOx to the atmosphere. (Ostmann, 11)

Although mankind contributes a considerable amount of SO2 and NOx to the atmosphere,

thankfully it is the source over which we have real control.

There are ways of reducing man-made acid emissions. We can do things to make our

fossil fuels themselves cleaner, things we can do to make the smoke from industry cleaner, and we

can do things to make the emissions from cars cleaner and/or use less fossil fuels in cars. Another

important thing we can do to reduce the acid rain problem is conserve energy. Every time we use

a kilowatt-hour, some SO2 and NOx has to be released into the atmosphere (assuming that your

power comes from a fossil fuel-fired power plant).

There are many ways we can make our industries run cleaner. We can actually clean coal

before it is burned. It can be crushed and washed in water or go through an electrostatic process

to take out the sulfur. We can remove much of the sulfur in oil by refining or distilling it and then

reacting it with hydrogen. (McCormick, 21)

"Because nitrogen oxides are formed by burning fuels reacting with nitrogen in the air, they can be reduced by lowering the combustion temperature and reducing the time air stays in the combustion chamber." (McCormick, 22)

Even after the fossil fuel is burned, things can be done with the smoke to make it cleaner by

filtering it. In cars, exhaust gases can be put through a catalytic converter attached to the exhaust.

The gases react with the chemicals in the filter, reducing hydrocarbon and NOx emissions by up to

90% (McCormick, 23)

Many processes are used to clean coal smoke before it is released into the atmosphere. In

wet scrubbing,

"Coal is burned in [the] furnace or boiler. Fans pull resultant gases through [a] precipitator where fly ash is removed. [A] Damper directs gases to scrubber spray tower where [the slurry of water and chemicals is sprayed to remove SO2 and remaining ash. Clean gases then go up [the] stack. Liquid chemicals [which were] used to absorb SO2 drains into reaction tank where sulfur is removed through a chemical process. Bleed pump routes it to clarifier from which it drains to sludge disposal pond." (Ostmann, 161)

(look at Coal Scrubber diagram for visual representation)

This is the oldest and most common way of cleaning out coal smoke. Used in conjunction with

washing the coal before burning it, these methods can be quite effective. The structure used for

this process is huge, being about 600 feet long and 10 stories high. Between 1 and 3 percent of

the energy produced in burning 10,000 tons of coal daily in a typical 900 megawatt power plant is

taken up by running the scrubber. Better forms of scrubbing coal smoke have been developed in

the last few decades. "Dry scrubbing" is much more water and energy efficient and is not as

expensive as wet scrubbing is. Regenerative scrubbing is also a process used to clean coal smoke.

Dry and wet scrubbing create great amounts of sludge though, and regenerative scrubbing avoids

this problem by converting the SO2 into pure sulfur. This pure sulfur can be put to good use to

replace part of the asphalt needed for road resurfacing. The Canadians are already researching

uses for this waste sulfur. Unfortunately, in 1982 no full-size US power plants were equipped

with dry or regenerative scrubbing. (Ostmann, 160-162)

A large reason we have an acid rain problem is that not too many power plants use sulfur

control measures. In 1982 (the year my source was copyrighted), only about 15 percent of the

US's coal fired power plants were equipped with SO2 scrubbers. Scrubbers are very expensive -

about 15% of the cost of a new, coal-fired, power plant is the scrubber. A new plant cost about

$800 million in 1980. A new coal power plant emits about 33 million pounds of SO2 and about

28 million pounds of NOx annually. It cost more to install scrubbers in an old plant than it is to

build them with a new power plant and the greater expense must be paid for in a shorter amount of

time, so there are very few old power plants with scrubbers. (Ostmann, 162-163)

The emissions from these dirty power plants and other sources of toxic emissions can have

great consequences. Much of the SO2 and NOx in these fumes doesn't rise very far and returns to

earth quickly in the form of dry deposition, or acid dust. The lion's share of the remaining SO2

and NOx is carried far from its source, maybe 620 miles (1000 km) from the source, bonds with

water suspended in the air, and falls to earth in the rain as wet deposition such as acid rain, hail, or

snow. Acid rain can help make ozone, which is a very harmful pollutant when found in the lower

atmosphere. This acid deposition, whether dry or wet, can be extremely bad for the environment.

(McCormick, 6-9)

This acid rain can chew up and spit out the very processes of life which allow us and other

plants and animals to survive on this good green earth. If you dipped your hand in hydrochloric

acid, the tissues of your hand would be damaged severely. Just like how some acids can hurt

humans by direct contact, many organisms are vulnerable to other types of acid contact.

"Scientists already know a great deal about how acidification can disrupt the natural order from the level of the molecule to the scale of whole populations:

- Enzymes, which catalyze vital reactions inside cells, are dependent on the acidity of the surrounding environment and are rendered less effective or totally inactive by increases in acid levels.

- Proteins, which comprise a significant part of the matter in all cells, undergo changes in geometry and function when altered.

- Organisms generally cannot reproduce and maintain themselves in optimal fashion unless their environment stays within a fixed range of acidity.

- Acidification of an environment frees up toxic metals such as aluminum, mercury, and lead that would otherwise stay safely bound.

- Acidification limits the diversity of an ecosystem by preventing the establishment or flourishing of acid-sensitive species." (Ostmann, 21)

These effects can be quite devastating on many systems of organisms.

Perhaps the life system most easily effected by acid rain is the freshwater lake or stream.

"Acid and most water creatures, large and small, just do not mix." (Ostmann, 21)

Acidified water seeps insidiously into lakes from under the ground, washes in from the surface of

the earth, flows in from rivers, or falls into lakes as acid dust or acid rain. When the pH of a

freshwater body reaches a certain threshold, fry (young fish) begin to die. In an hypothetically

recently acidified lake, there are 1, 2, 3 year old fish. Then the 3yr old fish eventually die of

natural causes (but speeded to their deaths by the effects of acidification). None of the eggs laid

by the young fish hatch due to the acidification of the lake. Then we have 2 and 3 year old fish.

The 3 year olds die. The eggs laid by the 2 year old fish don't hatch. Then there are only 3 year

olds. These old fish don't lay eggs, so when they die there are no more fish left in the lake. The

animals that eat the fish, like bears and herons, run out of food at that lake and have to go

somewhere else for food.

When acid rain falls into a lake, some of the acid is neutralized by alkaline substances in the

lake and in the underlying rock. An example of this neutralization is when you drop a teaspoon of

vinegar into a bowl full of baking soda. The vinegar will react with an amount of baking soda and

both will be turned into a neutral substance. There will still be baking soda left over though.

Many lakes which rest on limestone, a basic substance, have a large neutralizing capacity. Those

lakes which have little of this "buffer" are extremely vulnerable to acidification, though. Much of

the Northeast, Eastern Canada, the area just south of the Great Lakes, and the Appalachians

fall into this category of buffer-deficiant geography (Ostmann, 40-41) (see diagram).

When acid comes into contact with the rock on the bottom of a lake, toxic metals such as

aluminum and mercury are leached out of the rock and permeate everything in the lake.

"You are glumping the pond where the Humming-Fish hum. They can no longer hum for their gills are all gummed." - Dr. Seuss, "The Lorax"

The above quote is from "The Lorax", a film by Dr. Seuss. It is usually considered a film for

children, but indirectly it deals with the problem of acid rain. The acid is "glumped" into ponds via

the rain, and liberates toxic metals from the local rock. These toxic metals are bad for the fishes'

gills, and the fish produce a white gummy substance to avoid contact with excessive amounts of

the toxic metals. The fishes' gills get all gummed and they can't survive for want of oxygen. The

aluminum and mercury build up inside the fish from what they eat in the acidified pond, and

sometimes these fish can be so permeated with the toxic metals that they are poisonous to man.

You probably have seen notices near lakes warning fishermen of the mercury content of the fish of

that pond and telling them not to eat more than a certain number of fish from that body of water

each week or month. The toxic metals are also poisonous to the fish and kill the fish directly. The

liberation of toxic metals is a great concern within the acid rain dilemma.

Strangely enough, many acidified lakes look beautiful and pristine. That is because much

of the life in them has been wiped out by acid rain. Also, dust and other kinds of sediment are

often trapped on the lake bed by sphagnum moss, which is extremely acid tolerant. A acidified

lake is as barren as a desert though, and this beauty is only skin deep. (McCormick, 16)

Many lakes that you and I visit, and many that you and I don't have been affected by acid

rain. Many lakes in the Adirondacks have been affected greatly, as this quote demonstrates:

"In the 1930s almost all high Adirondack lakes - those over 2000 feet in elevation - contained fish and were popular fishing spots. About 1950, however, visitors and park officials began to see fewer and fewer fish. A number of causes were suggested, such as excessive beaver activity or

windstorm damage to the lake watersheds.... Finally, in 1975, a Cornell University scientist discovered why the fish were disappearing. Carl Schofield's survey of the Adirondack lakes

revealed that more than half were devoid of fish and most other forms of aquatic life. The explanation, according to Schofield, was acid rain and snow." (Ostmann, 38-39)

Lakes have also been affected in the following parts of the world: Ontario, the Boundary Waters

region of northeastern Minnesota, the Great Lakes, New England, areas of Nova Scotia, the

Rocky Mountains, the Sierra Nevadas, the Appalachians, Florida, southern Sweden, southern

Norway, and even Venezuela. (Ostmann, 39) In Sweden, over 18,000 lakes have been acidified.

(McCormick, 31) It is quite distressing to see so many lakes rendered devoid of most of their

aquatic life.

Acid rain also affects plants. When acid rain falls onto soil which is rich in certain minerals

crops, plants, and trees need to prosper, the soil can often neutralize the acid rain. This

neutralization interferes with the minerals and seems to reduce the prosperity of plants. Barley, for

example, grows 25 to 40 percent less in a sulfuric atmosphere. Tobacco can be affected by ozone

damage. This ozone damage shows first on the leaves. Until the 1950s this damage was called

weather fleck. It is now known to be ozone damage. (McCormick, 15)

Trees are also something very important to our planet being affected by acid rain. Trees in

the Black Forest and in southern Sweden have been affected greatly by acid rain. (McCormick,


"When acid rain falls onto its leaves, a tree will absorb alkalines from the soil, to counter the effect of the acid. As a result, the soil becomes more acid. Rain falling directly onto the soil also increases its acidity. Acid water moves through the soil, washing out nutrients and releasing poisonous metals, some of which are absorbed by the tree roots. It can be many years before the damage begins to show, and by then a whole forest may be affect." (McCormick, 14)

The death of trees is a very important consideration when looking at the acid rain problem.

The health of humans is also compromised by the existence of the acid rain problem. In

big cities, acid smogs are common. Dry acid deposition creates these acid smogs. Los Angeles,

Athens, and Mexico City have very bad smogs. London used to have very serious smogs - in

1952 a winter smog speeded the deaths of 4000 people, most of whom were sick or elderly. This

shocked the government into placing air pollution controls on London, and now London has

cleaner air than many other cities. (McCormick, 9) In some parts of Sweden, the local drinking

water is so polluted that it is not potable for children. (McCormick, 31)

Acid rain also is harmful to the constructs of humankind. Architecture, monuments, paint,

cars, and even steel bridges are corroded by acid rain. It has been estimated that between 1961

and 1986 the Parthenon has taken more damage from corrosion than in the past 2400 years from

natural forces. The Statue of Liberty, the Taj Mahal, and St. Paul's Cathedral have all been

corroded greatly by air pollution. It is quite sad to see a regal statue corroded in a matter of

decades instead of millennia. (McCormick, 18)

Since the Middle Ages, people have realized that things were going wrong with the rain,

especially in highly industrialized areas. The English exemplify this early acid rain awareness best.

As early as 1257, Queen Elanor of Aquitane, wife of Henry III, complained of evil-smelling British

air. This bad smelling air was actually a result of coal being burned in London and other places

around Britain, although that was not completely understood at the time. By the late 1280's, the

air problem was so bad that two commissions were appointed to deal with the problem. They did

nothing, although coal burning was banned during Parliament sessions for a time. By the 1600's

people began to realize the dangers of coal smoke. In 1620 King James I

"was moved with compassion for the decayed fabric [of Saint Paul's Cathedral]... near approaching ruin approaching ruin by the corroding quality of the coal smoke... where unto it had long been subject." (Ostmann, 24)

In 1661 John Evelyn wrote in his work, "Fumifugium", that because of "Clouds arising from

those great Fires, the Aer is so distemper'd and such unreasonable and unnatural storms are

engendered." According to Peter Brimblecombe (an English acid rain researcher), the English no

really feasible alternative to the burning of coal. They couldn't use less polluting wood because a

lot of the English forests were destroyed or undergoing this process. People tried to limit the use

of coal, suggest alternatives, or relocate industries, but in English society at the time the power of

industry and capital were growing rapidly and most of these attempts just petered out. The

factories created huge smokestacks to allow the coal smoke to drift away on the wind, but this

really didn't solve anything and is quite similar to our "modern" ways of dealing with coal and oil

smoke. (Ostmann, 23-25)

Since 1900, many advances in the awareness of the acid rain problem have been made.

Svante Oden, a scientist in Sweden, was and is instrumental in raising worldwide awareness about

the acid rain problem. In 1967 Svante Oden did some preliminary research which indicated that

the rain over parts of southern Scandinavia was becoming increasingly acidic. That summer, Ulf

Lunden, then a fisheries inspector for the city of Uddevalla on the southwest coast of Sweden, told

Oden that he had found some lakes in that area which had become devoid of fish and some lakes

where the fish were dying off. Lunden didn't know why the fish were dying but did some pH tests

on water from those lakes and found that the pH of the affected lakes seemed much lower than

normal. Oden realized that there was a connection between the pH of these lakes and the

disappearance of the fish (see graph of Tovdal watershed). This was the beginning of modern

scientific awareness of the overly acidified precipitation dilemma. As early as the early 1900s,

people in Norway noticed that there were less young fish in many rivers each year. Something had

to be done. (Ostmann, 87-89)

Since Oden's realization of the acid rain problem, many papers have been written on the

subject of acid rain. In 1972 Sweden presented a paper entitled "Air Pollution Across National

Boundaries" to the United Nations Conference on the Environment in Stockholm. This was a

groundbreaking paper because it was the first to focus the attention of the world on acid rain.

(Ostmann, 89-90)

The environmentalists were very concerned about the acid rain situation in November

1979. More than 800 people, including environmentalists, government officials, scientists, and

political leaders met in Toronto for a two day conference on acid rain. This conference was called

the Action Seminar on Acid Precipitation (ASAP hereinafter). It urged the governments of the US

and Canada to reduce their acid-forming pollutant emissions by 50% in 10 years. This was the

peak of public concern about acid rain, but sadly it eventually pretty much petered out. (Ostmann,


The politicians haven't done much to help the acid rain situation. Air quality standards

were set by the 1970 Clean Air Act, but this did little to help the acid rain situation. The Clean Air

Act allows the use of tall smokestacks. These tall smokestacks just spread the acid around a little

more, and hurt more than help. Until the act is revised to ban tall stacks, it looks like business as

usual for the acid factories (coal burners). (Ostmann, 34-35)

As with many scientific arguments, your conclusion is based on whose numbers you use.

If you look at books written by the "What Acid Rain?" faction, you will see that they use their

own set of sources, while the mainstream viewpoint books use their own set of sources. It is my

opinion that acid rain may be partially a natural adjustment but is mostly a problem created by

man's blatant SO2 and NOx emissions. I think that if we make sensible changes to our industries,

we can help alleviate the acid rain problem. I think that if we continue polluting at our current

rate, we are in for a lot of environmental trouble in a few decades. One person cannot make the

world's industry change, and industry will probably not change of its own accord. Only if many

people get together, can something be done about this grievous threat to earth's environmental


Works Cited

"ACID RAIN." Online. Internet.


"Acid Rain." Online. Internet. 4-27-98.

Bennett, Mark. "Acid Rain." Online. Internet. 4-27-98.

Boyle, Robert H. ACID RAIN. New York: Nick Lyons Books, 1983.

Britton, J. "Canadian Coalition on Acid Rain." Online. Internet. 4-27-98.

Francis, B. Magnus. TOXIC SUBSTANCES IN THE ENVIRONMENT. Newyork, Chichester,

Brisbane, Toronto, Singapore: John Wiley & Sons, Inc., 1994.

Meyerson, Dave. "Acid Rain." Online. Internet. 4-27-98.

McCormick, John. ACID RAIN. New York, Toronto: Gloucester Press, 1986.


City: Julian Messner, 1986.

Ostmann, Robert. ACID RAIN. Minneapolis: Dillon Press, 1982.



Washington, D.C.: Regnery Gateway, 1990.

"US EPA Acid Rain Homepage." Online. Internet. 4-27-98.

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